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9-Borabicyclo[3.3.1]nonane 9-硼雙環[3.3.1]壬烷

規格: 0.5 M solution in THF, SpcSeal
CAS: 280-64-8
產品編號: H24421
MDL: MFCD00074742
品牌: INFI
Chemical Name9-Borabicyclo[3.3.1]nonane
CAS Number280-64-8
EC Number206-000-9
Beilstein Registry Number605509
MDL NumberMFCD00074742
Synonym 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {
PubChem Substance ID6327450
Chemical Name Translation9-硼雙環[3.3.1]壬烷
InChIKeyFEJUGLKDZJDVFY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222630
InChIInChI=1S/C8H14B/c1-3-7-5-2-6-8(4-1)9-7/h7-8H,1-6H2
Canonical SMILESC1(B2)CCCC2CCC1
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
  • S30 Never add water to this product 切勿將水加入該產品中；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴適當的手套和眼睛/面保護；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 著火時使用（指明具體的消防器材種類，如果用水增加危險，注明“禁止用水”
  • S7/8 Keep container tightly closed and dry 保存在嚴格密閉容器中，保持干燥；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14 Reacts violently with water 遇水會猛烈反應
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應，釋放出高度可燃氣體
    • R15 Contact with water liberates extremely flammable gases 遇水會釋放出極端易燃的氣體
    • R19 May form explosive peroxides 可能生成易爆的過氧化物質
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮膚接觸和不慎吞咽有害
    • R36/37 Irritating to eyes and respiratory system 對眼睛和呼吸系統有刺激性
    • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
    • R38 Irritating to skin 刺激皮膚
    • R40 Limited evidence of a carcinogenic effect 有限證據表明其致癌作用
    • R48/20
    • R51/53
    • R62 Possible risk of impaired fertility 有削弱生殖能力的危險
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能傷害肺部器官
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能導致嗜睡和昏厥
      Precautionary statements
      • P201 Obtain special instructions before use. 使用前獲取專門指示。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
      • P222 Do not allow contact with air. 不要與空氣接觸。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能，因為會劇烈反應可能產生閃火。
      • P231+P232
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
      • P273 Avoid release to the environment. 避免釋放到環境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
      • P301+P310
      • P301+P330+P331
      • P302+P334
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
      • P321 Specific treatment (see … on this label). 具體治療（見本標簽上的）。
      • P331 Do NOT induce vomiting.. 不要催吐。
      • P335+P334
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗凈后方可重新使用。
      • P370+P378
      • P402+P404
      • P403+P235
      • P405 Store locked up. 上鎖保管。
      • P422 Store contents under… 存儲目錄在…之下。
      • P501 Dispose of contents/container to..… 處理內容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
        • H250 Catches fire spontaneously if exposed to air 暴露于空氣自發著火
        • H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體，可自燃。
        • H304 May be fatal if swallowed and enters airways 吞食和進入呼吸道可能致命
        • H314 Causes severe skin burns and eye damage 導致嚴重的皮膚灼傷和眼睛損傷
        • H315 Causes skin irritation 會刺激皮膚
        • H319 Causes serious eye irritation 嚴重刺激眼睛
        • H335 May cause respiratory irritation 可能導致呼吸道刺激
        • H336 May cause drowsiness or dizziness 肯能導致嗜睡或頭暈
        • H351 Suspected of causing cancer 懷疑致癌
        • H361 Suspected of damaging fertility or the unborn child 懷疑對生育能力或未出生嬰兒造成傷害
        • H373 May causes damage to organs through prolonged or repeated exposure 長期或頻繁接觸可能會損傷器官
        • H411 Toxictoaquaticlifewithlonglastingeffects 對水生生物有毒性并具有長期影響。
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes 4.3 F,Xn F,Xn,N F,Xn,Xi,N F;Xi
          UN Number 3399
          Packing GroupI
          Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
        • 使用 9-BBN 對相應環狀縮醛進行還原以鑒別對稱二醇。
        • 選擇性硼氫化還原試劑。
        • Reactant for:
        • • Linear SPPS synthesis of ubiquitin derivatives
        • • Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
        • • Intramolecular insertion of alkenes into palladium-nitrogen bonds
        • • Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
        • • Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids
          • 280-64-8 H24421 9-Borabicyclo[3.3.1]nonane 9-硼雙環[3.3.1]壬烷

          化學屬性

          Mol. FormulaC8H15B
          Mol. Weight122.02
          Density0.894
          Boiling Point68-70 °C
          Flash Point-19°(-2°F)
          Solubility起反應
          TSCANo
          Stability對空氣和水分敏感
          Danger-Level甲類
          pH:A

          *以上化合物性質(zhi)及(ji)應用等(deng)信息僅供參考